Structure and Dynamics of All of the Stereoisomers of Europium Complexes of Tetra(carboxyethyl) Derivatives of Dota: ring Inversion is Decoupled from Cooperative Arm Rotation in the RRRR and RRRS Isomers

Submitted by Anonymous on Fri, 10/15/2021 - 15:22

Description:

The absolute configuration of the four stereoisomeric α-substituted derivatives of dota has been defined; in their Eu complexes, 2D-NMR methods have revealed that in solution ring inversion is independent of pendant arm rotation and the (RRRR)-[EuL1a] complex which in the solid state crystallises as a square antiprismatic structure.

1998-01-01T08:00:00Z

Subject:

Chemistry

Type:

text

Raw Url:

https://pdxscholar.library.pdx.edu/do/oai/?metadataPrefix=oai_dc&verb=GetRecord&identifier=oai:pdxscholar.library.pdx.edu:chem_fac-1429

Source:

Chemistry Faculty Publications and Presentations

Repository Record Id:

oai:pdxscholar.library.pdx.edu:chem_fac-1429

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