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Phase Considerations in the Gas/Particle Partitioning of Organic Amines in the Atmosphere

Description: 
Amines in the atmosphere are of interest because of their likely role in new particle formation, and because of anthropogenic emissions of amines at post-combustion carbon capture (PCCC) facilities. A conceptual framework for considering the partitioning of a monobasic amine (Am = unprotonated "free-base form) from the gas phase to atmospheric particulate matter (PM) is presented for cases when the PM may be composed of multiple liquid phases. Three types of liquid phases are considered as being individually or simultaneously possible for absorptive uptake of atmospheric amines: w) a mostly water phase; α ) a mostly (by mass) organic phase that has at least some polarity (e.g., predominantly secondary organic aerosol (SOA), and may contain significant water on a mole fraction basis); and ß) a mostly organic phase that is less polar than an a phase (e.g., predominantly primary organic aerosol (POA), containing little water). That one or more salts may contain the aminium ion AmH+ (formed by protonation of Am) is subject to the fact that the trace levels of individual amines in the atmosphere make formation of pure solid such as AmHHSO4(s) exceedingly unlikely: when solid salts of AmH+ are indeed present, by far the most likely form is as a solid solution, e.g.,(NH+4)1-y(AmH+)HSO-4(s) where y <<1.
Record Format: 
application/pdf
2015-09-28T07:00:00Z
Subject: 
Climatic changes -- Effect of human beings on
Air -- Pollution
Amines
Atmospheric aerosols -- Composition
Chemistry
Environmental Chemistry
Type: 
text
Raw Url: 
http://pdxscholar.library.pdx.edu/do/oai/?metadataPrefix=&verb=GetRecord&identifier=oai:pdxscholar.library.pdx.edu:chem_fac-1114
Source: 
Chemistry Faculty Publications and Presentations
Repository Record Id: 
oai:pdxscholar.library.pdx.edu:chem_fac-1114
SetSpec: 
publication:mcecs
publication:chem
publication:cengin
publication:clas
publication:communities
publication:chem_fac
publication:cengin_fac
Record Title: 
Phase Considerations in the Gas/Particle Partitioning of Organic Amines in the Atmosphere
https://pdxscholar.library.pdx.edu/chem_fac/114
info:doi/10.1016/ j.atmosenv.2015.09.056
https://pdxscholar.library.pdx.edu/context/chem_fac/article/1114/viewcontent/pankow_Phase_Considerations_Post_print.pdf
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