Description:
In the title compound, C3H9S+.CH3O3S-, a thermal decomposition product of dimethyl sulfoxide, both cation and anion lie on mirror planes. In the cation, the S atom lies 0.792 (2) Å out of the plane defined by the three C atoms, with S-C distances of 1.781 (2) and 1.786 (3) Å. In the anion, the S-O distances are 1.4556 (14) and 1.4646 (19) Å, and the S-C distance is 1.759 (3) Å.
Subject:
Organic cations -- Measurement
Sulfonium compounds -- Structure
Organic compounds -- Synthesis
Organic Chemistry
Raw Url:
http://pdxscholar.library.pdx.edu/do/oai/?metadataPrefix=&verb=GetRecord&identifier=oai:pdxscholar.library.pdx.edu:chem_fac-1064
Source:
Chemistry Faculty Publications and Presentations
Repository Record Id:
oai:pdxscholar.library.pdx.edu:chem_fac-1064
Record Title:
Trimethylsulfonium Methanesulfonate
https://pdxscholar.library.pdx.edu/chem_fac/66
info:doi/10.1107/S1600536801006651
https://pdxscholar.library.pdx.edu/context/chem_fac/article/1064/viewcontent/strongin_trimethylsulfonium.pdf